I think Paulie B had his 400 grooved for copper o-rings ... I don't believe there would be such a difference in heat transfer as to cause a problem ... the groove size for the viton o-ring is critical, I got a just bit sloppy regrooving after decking a yz250 jug and had a leak problem ... hope someone's ambitious enough to give it a try
I had a V8 Ford 289 grooved for copper "O" rings many years ago.
Not entirely successful in my opinion. They seemed to relax their seal over time, not very good for a street driven engine.
I have been a bit sour toward them ever since...
My KTMs run composite gaskets on the early engines and Viton "O" rings on the newer stuff, but they are water cooled so 220f max.
The "O" rings are very durable and seal very well, I just don't know how they would do with air cooled.
Groove size and tension is extremely critical for the copper rings, Viton (or rubber) a bit more forgiving.
Copper is an interesting choice for a gasket. It was an old favourite many years ago because of its softness and ease of shaping. Soft aluminum and steel sheet was also used. I think that heat transfer rate of these metals might have just been incidental to their softness.
Asbestos cored composite gaskets pretty much supplanted copper after WWII because of superior performance and material costs.
The search for asbestos substitutes caused a lot of the head gasket failures that were so common in the 1980s and 90s.
The less durable cores would rip, buckle and relax from head to block expansion movement.
Multilayer steel shim seems to be the favourite these days, relying on a Viton coating and the spring of the cupped steel edge to seal.
I appreciate all of your advice. It looks like someone has to jump in if we are going to find out what the water is like!
My son is putting together his stroker motor. If he gets a head turned (we are talking about a toroidal chamber design) we may try an "O" ring design.